A pressure enthalpy ph diagram exhibits the same features as a pn diagram. Adding steam or water liquid psychrometric chart the psychrometric chart is a variant of the mollier diagram used in some parts of the world. Properties of water and steam thermodynamic properties of. Clean steam in the pharmaceutical industry tim latham, m. Rosemer and dale upgraded the widely known ph and po 4 ratio according the boiler operating pressure. Here is a brief example to demonstrate how to create a pressureenthalpy \\log p,h\ plot for propane r290 with automatic isoline spacing. Clean steam is used in the pharmaceutical and healthcare industries in processes where the steam or its condensate can come into contact with a pharmaceutical or medical product and cause contamination. If the ph is lower than that, the water will start eating the pipes. Table a1e molar mass, gas constant, and criticalpoint properties table a2e idealgas specific heats of various common gases table a3e properties of common liquids, solids, and foods table a4e saturated watertemperature table table a5e saturated waterpressure table table a6e superheated water table a7e compressed liquid water table a8e saturated icewater vapor. So for example, a ph of 8 is ten times more acidic than a ph of 9, and one hundred times more acidic that a ph. The pressure enthalpy diagram for steam is an excellent tool to gain an understanding of the steam tables. System ph for steam and condensate became respectively 9. Pressureenthalpy diagram for water ohio university.
It comes into play with steam boilers because a ph between 7 and 9 slightly alkaline is just right. Superheated steam finds its application in steam power plants for the generation of electrical power. Enthalpypressure diagram of the refrigeration cycle. The international association for the properties of water. See also water enthalpy h and entropy s for figures and tabulated values at varying temperatures. Page 5 other chemical properties in water supplies can also affect good steam generation and vary from within each state and locality.
The international association for the properties of water and steam berlin, germany september 2008. How to read mollier diagram easy explain learn and grow. Steam thermodynamics industrial wiki odesie by tech. The diagram was created in 1904, when richard mollier plotted the total heat against entropy. Pressure enthalpy diagram melting line40 o 40 c2 02 0.
It is advisable to use steamtables or mollier chart directly for easy and accurate estimation of the properties of steam, such as pressure, temperature, specific volume, enthalpy, entropy etc. The simplest and most straight forward use case is the generation of plots with default isolines and spacing. Congruent phosphate control diagram trabalho premiado abtcp 2014. Comparison of the typical textbook diagram without arrows on the phscale axis to mathematicaltextbook diagrams e. It is written that the cost of refrigeration is maximum. Mollier diagram pro is the best program i have on my laptop. Figure 1 illustrates the typical ph and po 4 operating limits depending upon the operating pressure. Mollier diagram pro is an easy to use mollier diagram with which you can make calculations of air treatment processes. H 1 to h 2 is the adiabatic compression of the compressor for the simple refrigeration system without suction and discharge penalties h. The mollier diagram is useful when analyzing the performance of adiabatic steadyflow processes, such as flow in nozzles, diffusers, turbines and compressors. Co 2 mollier diagram pressureenthalpy diagram mollier chart in metric units excel file 569 kb.
We know, however, that there is a limit, beyond which water can only exist as a fog of liquid water. This diagram describes the relationship of pressure and enthalpy of a select refrigerant. Mollier diagram for watersteam engineering toolbox. Determine the desired or necessary steam quality dryness or degree of superheat. Engineering toolbox sketchup extension online 3d modeling. Superheated steam and steam phase diagram electrical4u. Software for plotting a comparison of actual cycle ph. The vapor is compressed, following the constant entropy line to. Pretreatment 44 disadvantages of ro as compared to a softener boiler pretreatment program include. This product can be injected into the feeding water pipe or into the hp drums. Enthalpy, entropy, mollier diagram and steam tables course no. Drawn with steamtab using the iapwsif97 formulation. T p sat volume,m3kg energy,kjkg enthalpy,kjkg entropy,kjkgk mpa vf vg uf ug hf hg hfg sf sg sfg 40 0. Percentage of dissolved gas increases with temperature and ph.
Thermodynamics enthalpy entropy mollier and steam tables i. Po box, the heath, runcorn, cheshire, wa7 4qx tele. The diagram above shows no limit to the amount of water that can be evaporated into air. A refrigeration engineer commonly uses a mollier diagram ln p, h of the refrigerant used in order to represent and study the behavior of the machine with steam compression see figure 6. As shown in the following figure, the ph diagram consists of pressure psia on the yaxis and enthalpy btulbm on the xaxis. Case1 the basics of refrigeration cycle ph diagram analysis. Units is to present the various properties of water and steam in a most concise form. Reviewed by faculty from other academic institutions. Pressureenthalpy diagram based on iapws95 formulation for general and scientific use 200f 300f 400f 500f 600f 700 f 800f 800 f f 1200f 100f 1500f s1.
In electrochemistry, a pourbaix diagram, also known as a potentialph diagram, e hph diagram or a peph diagram, maps out possible stable equilibrium phases of an aqueous electrochemical system. A ph level only a single digit away from these recommendations can make a dramatic difference. X steam, thermodynamic properties of water and steam. Of course in any phpc diagram the concentrations of all species can be read off for any phvalue that the system is titrated to, and thus major and minor species can be identified. The diagram below can be used to determine enthalpy versus entropy of water and steam. Vulcan recommends the water contain less than 60ppm of total dissolved solids tds and have a ph factor between 6. In the liquidvapor region in figure 11, water and steam exist together. The xaxis of this diagram is the overall molar metal ratio in the. A ph diagram can be constructed for any pure substance. This has been a useful text for the students of mechanical engineering for more than 30 years. It is important to understand both the steadystate load profile as well as the transient and instantaneous demands. If its higher than that, the water wont corrode metal, but it may begin to foam, and thats not good. The steam phase diagram the data provided in the steam tables can also be expressed in a graphical form.
The pressureenthalpy diagram describes the liquid, vapor and mix region of water. Steam quality ranges from 0 to 100% and is defined as the ratio of. In power generation, thermodynamics is the conversion of chemical energy into other forms of energy this article covers thermodynamics associated with steam and fluid systems. I use it for optimization of installations and to accurately determine whether heat wheels work correctly rene hemme, hemmeonderhoudsadvies.
The differential of the superheated steam energy between the turbine inlet and outlet causes the turbine rotor to turn. Predominant ion boundaries are represented by lines. In steam turbines, superheated steam enters at one end and exit from the other end into the condenser may be of water or air cooled type. Enthalpyentropy mollier diagram for steam mechanical. In order to properly understand this diagram, it is best to go through the vapor compression. Made by faculty at the university of colorado boulder, department of chemical and biological engineering. Steam purity versus steam quality steam purity is the condition of the steam in regards to the purity of the chemistry of the steam expressed as ppb parts per billion of tds, sodium, cation conductivity or silica in the steam steam quality is the condition of the steam in regards to the % of moisture or boiler water carryover in the steam. Add standard and customized parametric components like flange beams, lumbers, piping, stairs and more to your sketchup model with the engineering toolbox sketchup extension enabled for use with the amazing, fun and free sketchup make and sketchup pro. Add the engineering toolbox extension to your sketchup from the.
As there is no copper tube in the system, no restrictions for the upper ph. Clean and pure steam systems biopharmaceutical industry. As such a pourbaix diagram can be read much like a standard phase diagram with a different set of axes. The range between 7 and 12, both ammonium ions and dissolve gas exist together. The points which are required for engineering calculation are from h 1 to h 6 as shown in the figure 16. Thermodynamics is the physics that deals with the relationship between heat and other forms of energy. A basic understanding of thermodynamics is needed before learning how to improve plant efficiency. Please give some authentic reference to know the cost of steam and. Like the pn diagram, there are regions on a ph diagram in which two phases exist together. Attempts to readdress the types of steam used for key pharmaceutical manufacturing processes. Steam boiler diagram with parts for dummys electrical. Above ph 12, virtually all the ammonia will be present as a dissolved gas. The process transforming a mollier diagram to a psychrometric chart is shown below. Where temperature and ph favor removal of ammonia from solution.
402 1416 602 312 1577 1286 1190 567 536 1024 1264 98 1054 883 1451 1034 119 645 1503 1324 1403 1528 1158 1362 46 1286 1031 205 579 1353 1228 1216 1398